Dicarboxylic
acid is a compound containing two carboxylic acid, -COOH,
groups. Straight chain examples are shown in table. The
general formula is HOOC(CH2)nCOOH,
where oxalic acid's n is 0, n=1 for malonic acid, n=2 for succinic acid, n=3
for glutaric acid, and etc. In substitutive
nomenclature, their names are formed by adding -dioic'
as a suffix to the name of the parent compound. They
can yield two kinds of salts, as they contain two carboxyl
groups in its molecules. The range of carbon chain lengths is from 2, but the
longer than C 24 is very rare. The term long chain
refers to C 12 up to C 24 commonly. Carboxylic
acids have industrial application directly or indirectly
through acid halides, esters, salts, and anhydride forms,
polymerization, and etc. Dicarboxylic acids
can yield two kinds of salts
or esters, as they
contain two carboxyl groups in one molecule.
It is useful in a variety of industrial applications
include;
- Plasticizer for
polymers
- Biodegradable solvents and lubricants
- Engineering
plastics
- Epoxy
curing agent
- Adhesive
and powder coating
- Corrosion inhibitor
- Perfumery
and pharmaceutical
- Electrolyte
There are almost
infinite esters obtained from carboxylic
acids. Esters
are formed by removal of water from an acid and an alcohol. Carboxylic acid
esters are used as in a variety of direct and indirect applications. Lower chain
esters are used as flavouring base materials, plasticizers, solvent carriers and
coupling agents. Higher chain compounds are used as components in metalworking
fluids, surfactants, lubricants, detergents, oiling agents, emulsifiers, wetting
agents textile treatments and emollients, They are also used as intermediates
for the manufacture of a variety of target compounds. The almost infinite esters
provide a wide range of viscosity, specific gravity, vapor pressure, boiling
point, and other physical and chemical properties for the proper application
selections.
C
length (Straight)
|
Product
|
CAS
#
|
Melting
Point
|
Boiling
Point
|
C
2
|
Oxalic
Acid (Ethanedioic
Acid) |
144-62-7 |
189
- 191
C
|
Sublimes
|
C
3
|
Malonic
Acid (Propanedioic
Acid)
|
141-82-2 |
131 - 135
C |
Decomposes
|
C
4
|
Succinic
Acid (Butanedioic Acid)
|
110-15-6 |
185
- 190 C
|
235
C
|
C
5
|
Glutaric
Acid (Pentanedioic
Acid)
|
110-94-1 |
95
- 99
C
|
302
C
|
C
6
|
Adipic
Acid (Hexanedioic Acid)
|
124-04-9 |
151
- 153
C
|
265
C at 100 mmHg
|
C
7
|
Pimelic
Acid (Heptanedioic Acid)
|
111-16-0 |
105
- 106
C
|
212
C at 10 mmHg
|
C
8
|
Suberic
Acid (Octanedioic Acid)
|
505-48-6 |
143
- 144
C
|
230
C at 15 mmHg
|
C
9
|
Azelaic
Acid (Nonanedioic Acid)
|
123-99-9 |
100
- 103 C
|
237
C at 15 mmHg
|
C
10
|
Sebacic
Acid (Decanedioic Acid)
|
111-20-6 |
131
- 134
C
|
294
at 100 mmHg
|
C
11
|
Undecanedioic acid |
1852-04-6 |
109
- 110 C
|
|
C
12
|
Dodecanedioic acid |
693-23-2 |
128
- 129 C
|
245
C at 10 mmHg
|
C
13
|
Brassylic acid (Tridecanedioic acid) |
505-52-2 |
112
- 114 C
|
|
C
14
|
Tetradecanedioic acid |
821-38-5 |
126
- 128 C
|
|
C
15
|
Pentadecanedioic acid |
1460-18-0 |
|
|
C
16
|
Thapsic acid (Hexadecanedioic acid) |
505-54-4 |
124
- 126 C
|
|
C
18
|
Octadecanedioic
acid
|
871-70-5 |
|
|
|